Polymer Sciences: from Synthesis to Polymer Material (B-KUL-G0G96A)

6 ECTSEnglish39 First term
Ianiro Alessandro (coordinator) |  Goderis Bart |  Koeckelberghs Guy |  N. |  Ianiro Alessandro (substitute)
POC Chemie

  • The student has a detailed knowledge of and insight in the chemical, physicochemical and physical aspects that are dealt with in the course (more details in the respective OLA’s).
  • The student has knowledge of and insight in the importance of the “Chain of knowledge” (more details in the respective OLA’s).

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(Activity Chemistry of Polymers) 

  • The student can explain the difference between a chain growth and step growth mechanism.
  • The student can distinguish the different steps in a chain growth polymerization mechanism and can indicate the influence on the polymerization.
  • The student can compare the different ways in which vinyl monomers polymerize (radical, cationic, anionic) and can link these with the molecular structure of the monomer.
  • The student can explain the relation between the molecular structure of the monomer and the molar mass of the resulting polymer, the polymerization rate and the copolymerization parameters.

(Activity Physical Properties of Polymers) 

  • The student can give the definitions and the descriptions as well as explain the meaning of physicochemical and physical theoretical concepts and results dealt with in the course and clarify their importance and their interplay in the “Chain of knowledge”;
  • The student can give correct derivations, point out the used approximations and discuss and analyse the consequences and limitations of the approximations for the theoretical concepts and results given in the list “Theoretical concepts and results” available on Toledo;
  • The student can clarify and show the importance of the “Chain of knowledge” and of the theoretical concepts and results for polymer materials which are dealt with in the course and for new examples of polymer materials provided by the lecturer;
  • The student can define and then find with the available information search methods relevant (scientific factual) information that is required to bring the exercises and assignments to a successful end;
  • The student can apply the theoretical concepts and results in simple exercises and come up with concrete results and answers and place them in the context of the theoretical concepts;
  • The student can apply the theoretical concepts in integrating assignments (3 or 4, depending on the extend of the assignments) and come to concrete results and answers and place them in the context of the theoretical concepts;
  • The student can present the results of the assignments in a written report in the English language according to the guidelines “Reporting assignments” available on Toledo;
  • The student can use present-day ICT tools in the making and the reporting of the assignments;
  • The student can make a detailed time planning for an assignment, communicate and justify the time planning to the lecturer and, if needed,  adapt and evaluate the time planning.

  • The student has at least knowledge of the following mathematical and physical concepts and notions: vectors, functions, integrals, differentials, Fourier transfoms, complex numbers, series, energy, forces, viscosity, elasticity, electromagnetic radiation (visible light, IR, X-ray), index of refraction;
  • The bachelor has basic knowledge of atoms, molecules, bonds, molecular interactions, thermodynamic state functions (internal energy, enthalpy, entropy, Gibbs energy, Helmholtz energy) and derived properties (volume, pressure and temperature) or can acquire this basic knowledge autonomously;
  • The student can explain the mechanism of basic organic reactions, in accordance with the end terms of the bachelor of chemistry.
  • The student is capable to distinguish between the factors that stabilize/destabilize an organic compound and can indicate which of two analogue compounds is the most stable;
  • The student can independently derive first and second order reaction rate equations.

Activities

3 ects. Polymer Sciences: Physical Chemistry of Polymers (B-KUL-G0T88a)

3 ECTSEnglishFormat: Lecture19 First term
N. |  Ianiro Alessandro (substitute)
POC Chemie

Module Introduction:

  • Positioning of the course
  • Polymers and the chain of knowledge in polymer science

Module Physical Chemistry of Polymers

  • Single-chain description of polymers, ideal and real chains
  • The glassy state and the glass transition
  • Polymers solutions and blends
  • Rubber elasticity, polymer networks and polymer gels
  • Block copolymers in the bulk and solution, aspects of demixing

Course materials (lecture notes and powerpoint presentations ) are available on Toledo

Module Polymer Science: Introduction and Physical chemistry of polymers

  • Interactive lectures with demonstrations

3 ects. Polymer Sciences: from Synthesis to Polymer Material (B-KUL-G0G96a)

3 ECTSEnglishFormat: Lecture20 First term
POC Chemie

Module Polymer Chemistry
Classification of polymers
 

  • step-growth versus chain-growth, polycondensation versus polyaddition

Vinyl polymerization 

  • free radical polymerization
  • copolymerization, Q,e-scheme
  • anionic polymerization
  • cationic polymerization
  • coordination polymerization

Ring opening polymerization

  • anionic
  • cationic
  • metathesis

Living ionic polymerizations, NMP, ATRP
Polycondensations and step-growth polymerizations
Block-copolymers, star polymers, hyperbranched polymers

 
 
Module Physical Properties of Polymers

  • Crystallization and melting
  • Kinetics of crystallization
  • Hierarchical structures in polymer crystals

Course materials (lecture notes and powerpoint presentations ) are available on Toledo

Module Polymer Chemistry
Lectures
 
Module Physical Properties of Polymers
Lectures
 

Evaluation

Evaluation: Polymer Sciences: from Synthesis to Polymer Material (B-KUL-G2G96a)

Type : Exam during the examination period
Description of evaluation : Oral, Written
Type of questions : Open questions
Learning material : Calculator


The weighted score is calculated as follows:

  Module Polymer Chemistry: 1/3 of total

  Modules Introduction, Physical Chemistry of Polymers and Physical Properties of Polymers: 2/3 of total

 

To determine the final result for the exam the following criteria are used:

Criterion 1: at least 9/20 on the Module Polymer Chemistry

Criterion 2: at least 9/20 on the combination of the Modules Introduction; Physical Chemistry of Polymer; Physical Properties of Polymers.

 

When the student fulfils or fails on criterion 1 and criterion 2 the final result is equal to the weighted score.

When the student fulfils only 1 of the criteria (criterion 1 or criterion 2) the final result is equal to the smallest of [the weighted score, 9/2]